Category: Chemistry
The field of bone tissue engineering (BTE) is a promising avenue for addressing bone injuries and defects by constructing artificial scaffolds with bionic functionalities. Due to its unique 3D network structure, impressive mechanical properties, and excellent biocompatibility, bacterial cellulose (BC) has emerged as a captivating area of research in the realm of scaffold fabrication.
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Research revives 1800s photos
Researchers from Western University developed techniques for creating images from old, badly tarnished photographs. These techniques could also be used to study other historic artifacts and fossils and prevent corrosion in modern materials.
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Palladium nanocluster catalyst supports highly efficient and regioselective hydrogenation of epoxides
Alcohols are widely applied in life sciences and the chemical industry. Selective hydrogenation of epoxides using hydrogen molecules as a reductant is considered to be one of the most facile and atom-economical strategies for alcohol synthesis. However, controlling the regioselective ring opening of epoxides remains a challenge.
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Video: Is there a quick fix for ocean acidification?
Acidification is threatening the ocean’s ability to pull carbon dioxide out of our atmosphere, so scientists and startups are looking to ocean-sized antacids to raise its pH.
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New catalyst allows energy-friendly ammonia production for fertilizers and alternative fuel
Researchers led by Satoshi Kamiguchi at the RIKEN Center for Sustainable Resource Science (CSRS) in Japan have discovered a greener way to produce ammonia, an essential compound used in fertilizers.
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Researchers study effects of solvation and ion valency on metallopolymers
In a new paper published in JACS Au, researchers at the University of Illinois Urbana-Champaign analyzed the effects of solvation and ion valency on metallopolymers, with implications for critical materials recovery and recycling, and environmental remediation.
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Chemists devise easier new method for making a common type of building block for drugs
Ring-shaped chemical structures called saturated heterocycles are found in most FDA-approved drugs but are often difficult to create. Scripps Research chemists have just developed a surprisingly easy method for making many of these sought-after compounds from inexpensive starting chemicals.
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What heat can tell us about battery chemistry: Using the Peltier effect to study lithium-ion cells
Batteries are usually studied via electrical properties like voltage and current, but new research suggests that observing how heat flows in conjunction with electricity can give important insights into battery chemistry.
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Selective dual-wavelength olefin metathesis 3D-printing: How engineers are using SWOMP
3D printing has changed the world. It’s allowed the aerospace, medical, automotive, manufacturing and many other industries to customize parts and prototypes in ways they never could before. It has drastically increased flexibility and cost effectiveness while reducing waste and production time. But many 3D-printed materials aren’t the strongest.
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A physics-based predictive tool to speed up battery and superconductor research
From lithium-ion batteries to next-generation superconductors, the functionality of many modern, advanced technologies depends on the physical property known as intercalation. Unfortunately, it’s difficult to identify in advance which of the many possible intercalated materials are stable, which necessitates a lot of trial-and-error lab work in product development.
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How water guides the assembly of collagen, the building block of all humans
Water determines life: humans are three-quarters water. An international research team led by the University of Amsterdam (UvA) has now discovered how water also determines the structure of the material that holds us together: collagen.
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Paper coating biomaterials derived from anaerobic granular sludge may be cost-effective
The demand for paper and paperboard production continuously grows worldwide, particularly in the packaging industry. Due to the paper’s nature, it usually requires a surface coating to keep out water, oil, and other unwanted substances. These coatings can come with high financial and environmental costs. Using renewable coating materials that are also cost-effective can support sustainability strategies.
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Active copper structures in ZnO-Cu interfacial catalysis: CO₂ hydrogenation to methanol
Recent research published in the journal Science China Chemistry explores active copper structures in ZnO-Cu interfacial catalysis. Many experiments, including catalyst preparation, structural characterizations, catalytic performance evaluation, and DFT calculations, were performed.
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How aromatic dissolved organic matter affects organic micropollutant adsorption
Activated carbon is employed for the adsorption of organic micropollutants (OMPs) from water, typically present in concentrations ranging from ng L−1 to μg L−1. However, the efficacy of OMP removal deteriorates considerably due to competitive adsorption from background dissolved organic matter (DOM), present at substantially higher concentrations in mg L−1. Interpreting the characteristics of competitive DOM is crucial in predicting OMP adsorption efficiencies across diverse natural waters.
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Urchin-like CoFe-layered double hydroxide synthesized for high-efficiency electrocatalytic oxygen evolution
A research team led by Professor Wang Qi from Hefei Institutes of Physical Science, Chinese Academy of Sciences, has successfully synthesized a heterogeneous Ce@CoFe-LDH electrocatalyst by combining a simple hydrothermal method with rapid electrodeposition.
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Novel method improves Fourier transform infrared spectroscopy detection of ultra-low concentration trace substances
Recently, a research team led by Prof. Gao Minguang and Associate Prof. Li Xiangxian from Hefei Institutes of Physical Science (HFIPS), Chinese Academy of Sciences (CAS) has developed a spectral resolution enhancement method based on linear prediction theory to expand the application of FTIR (Fourier Transform Infrared Spectroscopy) technology in the detection of multi-component ultra-low concentration trace substances.
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Researchers develop amphibian-inspired camouflage skin
Inspired by amphibians such as the wood frog, investigators designed and synthesized a new type of camouflage skin involving one-dimensional photonic crystal structures assembled in three-dimensional flexible gels.
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Novel material degrades a widely used antibiotic that contaminates water
Levofloxacin is a widely used antibiotic prescribed to treat pneumonia, bacterial rhinosinusitis, bacterial prostatitis, pyelonephritis, urinary tract infections, skin disorders, and skin structure infections, among other conditions. The drug is prevalent in aqueous environments owing to its low degradability in wastewater treatment plants and is therefore considered an emerging pollutant.
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Metal-based electrocatalysts for ammonia electro-oxidation reaction to nitrate/nitrite: Past, present and future
Recently, a research team led by Prof. Ji Liang from Tianjin University, China, systematically introduced the research progress on the preparation of nitrate/nitrite by ammonia electro-oxidation reaction and proposed different strategies to enhance the electrocatalytic performance of the catalysts by modulating their composition and structure to inhibit the side reactions and electrode corrosion in the electrocatalytic process, and finally proposes the opportunities and challenges faced by ammonia electrocatalysis as well as its development trend.
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New ways to strengthen biomimetic spider-silk
Researchers at Karolinska Institutet have found that spiders have a special trick to make their silk strong, by using a natural biocompatible molecular enhancer. By using the same secret the researchers are able to create biomimetic spider-silk fibers in a non-toxic way. The study is published in Advanced Functional Materials.
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Researchers uncover a feasible biomarker for coffee consumption
Millions of people around the world drink coffee every day. The beverage contains a large number of bioactive substances, and its health effects on the human metabolism are therefore frequently subjects of scientific studies. In many of these studies, however, the data on coffee consumption is largely based on self-reporting by the participants and is therefore not always accurate. This can affect the scientific validity of nutritional studies.
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Bio-inspired materials showcase potential for protective equipment and textiles
Bio-inspired materials (BIM) are synthetic materials whose structure and properties are similar to natural materials or living matter. These materials have the potential to advance structural materials, textiles and protective equipment due to their durability and self-healing properties.
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A strategy to further boost the efficiency of copper indium gallium selenide solar cells
Until recently, chalcopyrite-based solar cells have achieved a maximum energy conversion efficiency of 23.35%, as reported in 2019 by Solar Frontier, a former Solar Energy company based in Japan. Further boosting this efficiency, however, has so far proved challenging.
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A new type of metallacrown ether based on polyoxometalate opens research opportunities
Crown ethers were discovered in 1967. They were then modified by adding a metal-containing unit, creating metallacrown ethers. These metallacrown ethers have been the subject of intensive research. Depending on the molecular makeup of the metallacrown ethers and their resultant architecture, the properties and, therefore, the uses of the metallacrowns can change. They have many different uses currently, and ongoing studies continue to expand their application.
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Chemical etching method opens pores for fuel cells and more
A chemical etching method for widening the pores of metal-organic frameworks (MOFs) could improve various applications of MOFs, including in fuel cells and as catalysts. Researchers at Nagoya University in Japan and East China Normal University in China developed the new method with collaborators elsewhere in Japan, Australia, and China, and their work was published in the Journal of the American Chemical Society.
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Researchers observe the effect of magnetic fields on electrocatalytic processes
A collaboration between research groups from ICIQ demonstrate how the presence of an external magnetic field alters the reaction mechanism of the electrocatalytic oxygen evolution reaction.
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A bright idea for recycling rare-earth phosphors from used fluorescent bulbs
Recycling facilities collect glass and mercury from thrown-away fluorescent bulbs, but discarded lighting could also supply rare-earth metals for reuse. The 17 metals referred to as rare earths aren’t all widely available and aren’t easily extracted with existing recycling methods.
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Biochemists discover compound that inhibits evolution of antibiotic resistance
Vanderbilt scientist Houra Merrikh led a team of researchers who discovered the first anti-evolution chemical compound that prevents drug resistance development in bacteria. The compound is also a drug development platform that targets antimicrobial resistance during treatment of infections with antibiotics and evolution in general, Merrikh said.
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Recycling research finds new process to transform glass fiber-reinforced plastic into silicon carbide
Glass fiber-reinforced plastic (GFRP), a strong and durable composite material, is widely used in everything from aircraft parts to windmill blades. Yet the very qualities that make it robust enough to be used in so many different applications make it difficult to dispose of—consequently, most GFRP waste is buried in a landfill once it reaches its end of life.
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AI-powered platform could help law enforcement get ahead of designer drugs
An online platform powered by deep learning can predict the makeup of new psychoactive substances to help law enforcement in the fight against dangerous drugs.
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Study elucidates regulation mechanism for electrocatalytic nitrate reduction
A research team led by Prof. Zhang Haimin from the Hefei Institutes of Physical Science of the Chinese Academy of Sciences has conducted a systematic study on the regulation mechanism of heterostructure bimetallic phosphide electrocatalysts to improve the performance of electrochemical nitrate reduction reaction.
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Towards the selective and energy-efficient synthesis of ethylene via carbon dioxide reduction
The synthesis of carbon-based chemicals via the electrochemical reduction of carbon dioxide (CO2) has become the key objective of numerous recent energy research efforts. While these studies have yielded promising results, enabling the production of various widely used chemicals, most proposed approaches exhibit poor energy efficiencies and selectivity.
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Hot stuff: A new thermal pathway for a high explosive
TATB (1,3,5-triamino-2,4,6-trinitrobenzene) is an important explosive compound because of its extensive use in munitions and worldwide weapons systems. Despite its importance, researchers have been trying to understand its response to temperature extremes for the past 50 years.
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Researchers design novel microfluidic module for controlling the porosity of manufactured materials
Porous materials are essential for many chemical processes, such as light harvesting, adsorption, catalysis, energy transfer, and even new technologies for electronic materials. Therefore, many efforts have been made to control the porosity of different manufactured materials.
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Using light to control the catalytic process
Nature is amazing. It has developed in living organisms the ability to regulate complex biochemical processes with remarkable efficiency. Enzymes, natural catalysts, play a pivotal role in this regulation, ensuring the fulfillment of various physiological needs throughout a cell’s lifespan.
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Chemical labeling method provides new approach for recording cellular activities
In living cells, a vast number of transient events occur simultaneously, each of them important for a given cell in carrying out its function. The faithful recording of these transient activities is a prerequisite for a molecular understanding of life, yet obtaining such recordings is extremely challenging.
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Tailoring morphology symmetry of bismuth vanadate photocatalysts for efficient charge separation
In a study published in the journal Science China Chemistry and led by Prof. Rengui Li (State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences), a distinct charge separation difference has been found via rationally tailoring the morphology symmetry of BiVO4 photocatalyst.
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Pharmacists propose ways to increase the activity of levofloxacin and overcome bacterial resistance
The antibacterial drug levofloxacin is used to treat pneumonia, sinusitis, genitourinary infections, and other diseases. It is included in the WHO Model List of Essential Medicines. In terms of its chemical structure, it is a third-generation fluoroquinolone—a completely synthetic substance of the quinolone type.
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Solar-driven green synthesis of epoxides
Research published in the journal Science China Chemistry is expected to serve as comprehensive background knowledge and to provide researchers with insight into the recent developments of solar-driven green synthesis of epoxides.
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Exploring microstructures for high-performance materials
In just the first few months of 2024, the journal Nature has published two scientific papers co-authored by Kun Luo, an Iowa State University postdoctoral research associate in materials science and engineering.
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New class of ‘intramolecular bivalent glue’ could transform cancer drug discovery
A breakthrough class of molecular glue identified at the University of Dundee could pave the way for a new generation of drugs to target cancers and neurodegenerative diseases.
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Unraveling the pH-dependent oxygen reduction performance on single-atom catalysts
A group of researchers has answered some pressing questions regarding a new, promising class of catalysts known as single-atom catalysts (SACs).
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Researchers conduct comprehensive review on preparation of MOF-based flame retardants via coordination bond cleavage
Since the first report of metal-organic framework (MOF)-based flame retardants in 2017, this research area has exploded. However, improving the flame-retardant efficiency of MOFs and expanding their application areas remain critical challenges. The physicochemical properties of MOFs are closely dependent on their topology, pore characteristics, and chemical composition, which can be modulated by targeted design.
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Coordination polymer crystals show promise as new generation of light sources for industry, medicine
New forms of the light-emitting materials called phosphors, with enhanced versatility relative to existing options, are being developed by researchers at the National Institute for Materials Science (NIMS) in Japan, with colleagues at Tokyo University of Science and Hokkaido University. Their work is published in the journal Science and Technology of Advanced Materials.
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Using metabolomics for assessing safety of chemicals may reduce the use of lab rats
Scientists have discovered a more robust way of grouping chemicals and using read-across for toxicological data to meet regulatory requirements, which could greatly reduce animal testing.
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Accelerating the discovery of single-molecule magnets with deep learning
Synthesizing or studying certain materials in a laboratory setting often poses challenges due to safety concerns, impractical experimental conditions, or cost constraints. In response, scientists are increasingly turning to deep learning methods that involve developing and training machine learning models to recognize patterns and relationships in data that include information about material properties, compositions, and behaviors.
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Researchers synthesize a new manganese-fluorine catalyst with exceptional oxidizing power
A research team, affiliated with UNIST has unveiled a cutting-edge catalyst with exceptional oxidizing power, capable of extracting electrons from compounds. Anticipated to revolutionize various fields, including the development of metal catalysts and synthetic chemistry, this catalyst marks a significant breakthrough in catalytic research.
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Chemists produce all eight possible variants of polypropionate building blocks from one starting material
To synthesize potential drugs or natural products, you need natural substances in specific mirror-image variants and with a high degree of purity. For the first time, chemists at the University of Bonn have succeeded in producing all eight possible variants of polypropionate building blocks from a single starting material in a relatively straightforward process. Their work has now been published in Angewandte Chemie International Edition.
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Smart e-nose uses self-heating temperature modulation to enable rapid identification of gas molecules
A recent study published in ACS Sensors highlights the development of a smart electronic nose (e-nose) by a research team led by Prof. Meng Gang from the Hefei Institutes of Physical Science of the Chinese Academy of Sciences.
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Applying green chemistry principles to iron catalysis
At the Leibniz Institute for Catalysis in Rostock, Dr. Johannes Fessler has developed new methods for the synthesis of drug precursors using catalysts made of iron, manganese and cobalt. Each of these three chemical elements has the potential to replace a number of noble metals that are commonly used in organic chemistry to catalyze fine chemicals.
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